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Zhang, Wen; Lu, Lingxiang; Zhang, Wendy; Wang, Yi; Ware, Skyler D.; Mondragon, Jose; Rein, Jonas; Strotman, Neil; Lehnherr, Dan; See, Kimberly A.; et al (, Nature)
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Lu, Lingxiang; Fu, Niankai; Lin, Song (, Synlett)We report the development of an electrocatalytic protocol for the chlorophosphinoylation of simple alkenes. Driven by electricity and mediated by a Mn catalyst, the heterodifunctionalization reaction takes place with high efficiency and regioselectivity. Cyclic voltammetry data are consistent with a mechanistic scenario based on anodically coupled electrolysis in which the generation of two distinct radical intermediates occur simultaneously on the anode and are both mediated by the Mn catalyst.more » « less
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Zhang, Wendy; Gu, Chaoxuan; Wang, Yi; Ware, Skyler D.; Lu, Lingxiang; Lin, Song; Qi, Yue; See, Kimberly A. (, JACS Au)
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